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NetLogo Models Library:
This model simulates the behavior of gas particles in a piston, or a container with a changing volume. The volume in which the gas is contained can be changed by moving the piston in and out. "Isothermal" means that the temperature of the gas is not changed by moving the piston.
This model is one in a series of GasLab models. They use the same basic rules for simulating the behavior of gases. Each model integrates different features in order to highlight different aspects of gas behavior.
The basic principle of the models is that gas particles are assumed to have two elementary actions: they move and they collide --- either with other particles or with any other objects such as walls.
This model is part of the Connected Mathematics "Making Sense of Complex Phenomena" Modeling Project.
The particles are modeled as hard balls with no internal energy except that which is due to their motion. Collisions between particles are elastic. Particles are colored according to speed --- blue for slow, green for medium, and red for high speeds.
Coloring of the particles is with respect to one speed (10). Particles with a speed less than 5 are blue, ones that are more than 15 are red, while all in those in-between are green.
Particles behave according to the following rules: 1. A particle moves in a straight line without changing its speed, unless it collides with another particle or bounces off the wall. 2. Two particles "collide" if they find themselves on the same patch (NetLogo's View is composed of a grid of small squares called patches). 3. A random axis is chosen, as if they are two balls that hit each other and this axis is the line connecting their centers. 4. They exchange momentum and energy along that axis, according to the conservation of momentum and energy. This calculation is done in the center of mass system. 5. Each turtle is assigned its new velocity, energy, and heading. 6. If a turtle finds itself on or very close to a wall of the container, it "bounces" -- that is, reflects its direction and keeps its same speed.
Pressure is calculated as the force per unit area (or length in this two-dimensional model). Pressure is calculated by adding up the momentum transferred to the walls of the box by the particles when they bounce off and divided by the length of the wall, which they hit.
Initial settings: - NUMBER-OF-PARTICLES: number of particles - INIT-PARTICLE-SPEED: initial speed of the particles - PARTICLE-MASS: initial mass of the molecules - BOX-WIDTH: width of the container - BOX-HEIGHT: height of the container
Other settings: - COLLIDE?: Turns collisions between particles on and off. It can be changed in the middle of the run.
The SETUP button will set the initial conditions. The GO button will run the simulation.
Pushing the MOVE-PISTON button allows you to reposition the piston by clicking on the view with the mouse, hence changing the volume. When this button is pressed, the model stops. Once the reposition is done, push the GO button to continue.
The intention in this model is for the user to quickly pull the piston back thus simulating quickly removing a plate. This means no particles collide with the piston as it is removed. However, we have left in code that allows the user to push the piston in and compress the gas. In this model, though, the collisions of the piston with the particles are ignored. Note that there's a physical impossibility in the model here: in real life if you moved the piston in you would do work on the gas by compressing it, and its temperature would increase. In this model the energy and temperature are constant no matter how you manipulate the piston, hence the name "isothermal". Nonetheless, the basic relationship between volume and pressure is correctly demonstrated here.
The physically accurate version of piston compression is shown in the "Adiabatic Piston" model.
Monitors: - PISTON POSITION: position of the piston with respect to the x-axis - VOLUME: volume (or area) of the piston - PRESSURE - AVERAGE SPEED: average speed of the particles - AVERAGE ENERGY: average energy of the particles, calculated as m*(v^2)/2.
Plots: - PRESSURE: pressure in the piston over time. - VOLUME: volume of the piston vs time. - WALL HITS PER PARTICLE: the number of wall hits averaged for the particles during each time unit - SPEED HISTOGRAM: particles' speed distribution - ENERGY HISTOGRAM: distribution of energies of all the particles, calculated as m*(v^2)/2.
How does the pressure change as you change the volume of the box by moving the piston? Compare the two plots of volume and pressure.
Measure changes in pressure and volume. Is there a clear quantitative relationship? Boyle's Law describes the relationship between pressure and volume, when all else is kept constant.
How can the relationship between volume and pressure be explained in terms of the wall hits? How does it relate to collisions among molecules?
What shapes do the energy and velocity histograms reach after a while? Why aren't they the same? Do the pressure and volume affect these shapes? How does changing the particles' mass or speed affect them?
Change different kinds of settings and observe the number of wall hits per particle. What causes this number to change? What changes do not affect this number? Can you connect these relationships with those between the number of particles and pressure? Volume and pressure?
How would you calculate pressure? How does this code do it?
Change the number, mass, and initial velocity of the molecules. Does this affect the pressure? Why? Do the results make intuitive sense? Look at the extremes: very few or very many molecules, high or low volumes.
Figure out how many molecules there really are in a box this size --- say a 10-cm cube. Look up or calculate the real mass and speed of a typical molecule. When you compare those numbers to the ones in the model, are you surprised this model works as well as it does?
Observe the number of wall hits per particle with and without collisions. Does this number change? Why?
If you change the number of particles in the piston: will the pressure change? will the number of wall hits change? Why?
Are there other ways one might calculate pressure?
When the piston is moved out, the gas is not evenly distributed for a while. What's the pressure during this time? Does this ever happen in the real world? What does pressure mean when it's not the same throughout a gas?
Notice how collisions are detected by the turtles and how the code guarantees that the same two particles do not collide twice. What happens if we let the patches detect them?
This model was developed as part of the GasLab curriculum (http://ccl.northwestern.edu/curriculum/gaslab/) and has also been incorporated into the Connected Chemistry curriculum (http://ccl.northwestern.edu/curriculum/ConnectedChemistry/)
If you mention this model or the NetLogo software in a publication, we ask that you include the citations below.
For the model itself:
Please cite the NetLogo software as:
Copyright 1997 Uri Wilensky.
This work is licensed under the Creative Commons Attribution-NonCommercial-ShareAlike 3.0 License. To view a copy of this license, visit https://creativecommons.org/licenses/by-nc-sa/3.0/ or send a letter to Creative Commons, 559 Nathan Abbott Way, Stanford, California 94305, USA.
Commercial licenses are also available. To inquire about commercial licenses, please contact Uri Wilensky at email@example.com.
This model was created as part of the project: CONNECTED MATHEMATICS: MAKING SENSE OF COMPLEX PHENOMENA THROUGH BUILDING OBJECT-BASED PARALLEL MODELS (OBPML). The project gratefully acknowledges the support of the National Science Foundation (Applications of Advanced Technologies Program) -- grant numbers RED #9552950 and REC #9632612.
This model was developed at the MIT Media Lab using CM StarLogo. See Wilensky, U. (1993). Thesis - Connected Mathematics: Building Concrete Relationships with Mathematical Knowledge. Adapted to StarLogoT, 1997, as part of the Connected Mathematics Project. Adapted to NetLogo, 2002, as part of the Participatory Simulations Project.
This model was converted to NetLogo as part of the projects: PARTICIPATORY SIMULATIONS: NETWORK-BASED DESIGN FOR SYSTEMS LEARNING IN CLASSROOMS and/or INTEGRATED SIMULATION AND MODELING ENVIRONMENT. The project gratefully acknowledges the support of the National Science Foundation (REPP & ROLE programs) -- grant numbers REC #9814682 and REC-0126227. Converted from StarLogoT to NetLogo, 2002.